Grasas y Aceites, Vol 66, No 3 (2015)

Characterization of grape seed oil from wines with protected denomination of origin (PDO) from Spain


https://doi.org/10.3989/gya.1063142

J. C. Bada
Instituto de Productos Lácteos de Asturias-IPLA-CSIC, Spain

M. León-Camacho
Instituto de la Grasa-CSIC, Spain

P. Copovi
Instituto de Productos Lácteos de Asturias-IPLA-CSIC, Spain

L. Alonso
Instituto de Productos Lácteos de Asturias-IPLA-CSIC, Spain

Abstract


The aim of this study was to determine the composition and characteristics of red grape seed oils (Vitis vinifera L) from wines with protected denomination of origin (PDO) from Spain. Eight representative varieties of grape seed oils from the Spanish wine Ribera del Duero (Tempranillo), Toro (Tempranillo), Rioja (Garnacha), Valencia (Tempranillo) and Cangas (Mencia, Carrasquín, Albarín and Verdejo) were studied. The oil content of the seeds ranged from 13.89 to 10.18%, and the moisture was similar for all the seeds. Linoleic acid was the most abundant fatty acid in all samples, representing around 78%, followed by oleic acid with a concentration close 16%, the degree of unsaturation in the grape seed oil was over 90%. β-sitosterol and α-tocopherol were the main sterol and tocopherol, reaching values of 77.31% and 3.82 mg·100 g−1 of oil, respectively. In relation to the tocotrienols, α-tocotrienol was the main tocotrienol and accounted for 13.18 mg·100 g−1 of oil.

Keywords


Fatty acids; Grape; Oil; Seed; Sterols; Tocopherol; Tocotrienols

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References


Anonymous. 1999. User's Guide to MSTATC. An analysis of agronomic research experiments. Michigan State University. USA.

Agriview. 2008. AGV - Wine - General Balance Sheet European Union. Historique des indicateurs les plus utilisés dans le secteur vin, par campagne et par et at membre.

Bail S, Stuebiger G, Krist S, Unterweger H, Buchbauer G. 2008. Characterisation of various grape seed oils by volatile compounds, triacylglycerol composition, total phenols. Food Chem. 108, 1122–1132. http://dx.doi.org/10.1016/j.foodchem.2007.11.063 PMid:26065780

Baydar NG, Ozkan G, Celtin ES. 2007. Characterization of grape seed and pomace oil extracts. Grasas Aceites 58, 29–33.

Beveridge THJ, Girard B, Kopp JC, Drover G. 2005. Yield and composition of grape seed oils extracted by supercritical carbon dioxide and petroleum ether: varietal effects. J. Agric. Food Chem. 53, 1799–1804. http://dx.doi.org/10.1021/jf040295q PMid:15740076

Crew C, Hough P, Godward J, Brereton P, Lees M, Guiet S, Winkelman W. 2006. Quantitation of the main constituents of some authentic grape seed oils of different origins. J Agric. Food Chem. 54, 6261–6264. http://dx.doi.org/10.1021/jf060338y PMid:16910717

Europen Union, Official Diary, reglament n°. 479/2008.

Furiga A, Lonvaud-Funel A, Badet C. 2009. In vitro study of antioxidant capacity and antibacterial activity on oral anaerobes of a grape seed extract. Food Chem. 113, 1037–1040. http://dx.doi.org/10.1016/j.foodchem.2008.08.059

Freitas LS, Jacques RA, Richter MF. 2008. Pressurized liquid extraction of vitamin E from Brazilian grape seed oil. J. Chromatogr. A, 1200, 80–83. http://dx.doi.org/10.1016/j.chroma.2008.02.067 PMid:18343386

International Union of Pure and Applied Chemistry (IUPAC). 1987a. Standard Methods for the Analysis of Oils, Fats and Derivatives: Method 1122. Determination of oil content (extraction method). 7ªedn. Eds. C. Paquot, A. Haufenne. Blackwell Scientific Publications, Oxford, UK, 1987d, pp. 14–16.

International Union of Pure and Applied Chemistry (IUPAC). 1987b. Standard Methods for the Analysis of Oils, Fats and Derivatives: Method 1121. Determination of moisture and volatiles matter content. 7ªedn. Eds. C. Paquot, A. Haufenne. Blackwell Scientific Publications, Oxford, UK, pp. 13–16.

International Union of Pure and Applied Chemistry (IUPAC). 1987c. Standards Methods for the Analysis of Oils, Fats and Derivatives. Methods 2301. Preparation of the fatty acid methyl esters. 7ªedn. Eds. C. Paquot, A. Haufenne. Blacwell Scientific Publications, Oxford, UK, pp. 123–129.

International Union of Pure and Applied Chemistry (IUPAC). 1987d. Standard Methods for the Analysis of Oils, Fats and Derivatives: Method 2411. Identification and determination of tocopherols. 7ªedn. Eds. C. Paquot, A. Haufenne. Blackwell Scientific Publications, Oxford, UK, pp. 174–219.

Kin H, Kim SG, Choi Y, Jeong HS, Lee J. 2008. Changes in tocopherols, tocotrienols, and fatty acids contents. J. Am. Oil Chem. Soc. 85, 487–489. http://dx.doi.org/10.1007/s11746-008-1214-1

León-Camacho M, Morales MT, 2000. Gas and liquid chromatography: methodology applied to olive oil. In: Harwood JL, Aparicio R (eds). Handbook of olive oil: analysis and properties. Aspen, Gaithersburg, pp. 159–208.

Luque-Rodriguez JM, Castro MD, Lee J. 2008. Extraction of fatty acids from grape seed by superheated hexane. Talanta, 68, 126–130. http://dx.doi.org/10.1016/j.talanta.2005.04.054 PMid:18970294

Lutterodt H, Slavin M, Whent M, Turner E, Yu L. 2011. Fatty acid composition, oxidative stability, antioxidant and antiproleferative properties of selected cold-pressed grape seed oils anf flours. Food Chem. 128, 391–399. http://dx.doi.org/10.1016/j.foodchem.2011.03.040 PMid:25212146

Martinez Massanet G, Montiel JA, Pando E, Rodriguez LF. 1986. Study of agricultural by-products. II. Fatty acid composition of Palomino grapeseed oil. Grasas Aceites. 37, 233–236.

Mironeasa S, Leahu A, Codina GG, Stroe SG, Mironeasa C. 2010. Grape seed: physic-chemical, structural characteristics and oil content. J. Agro. Proces. Technol. 16, 1–6.

Oomah BD, Liang J, Godfrey D, Mazza G. 1998. Microwave, heating of grapeseed: Effect on oil quality. J. Agric. Food Chem. 46, 4017–4021. http://dx.doi.org/10.1021/jf980412f

Pardo JE, Fernández E, Rubio M, Alvarruiz A, Alonso GL. 2009. Characterization of grape seed oil from different grape varieties (Vitis vinifera). European J. Lipid Sci. Technol. 11, 188–193. http://dx.doi.org/10.1002/ejlt.200800052

Sineiro J, Dominguez H, Nú-ez MJ. 1995. Pepitas de uva como fuente de aceite y proteína. Aliment. Equipos Tecnol. 14, 49–56.

Tangolar SG, Ozugol Y, Tangolar S, Torun A. 2009. Evaluation of fatty acid profiles and mineral content of grape seed oil of some grape genotipes. Int. J. Sci. Nutri. 60, 32–39. http://dx.doi.org/10.1080/09637480701581551 PMid:17886077

Tecator. 2002. Aplication note, A3001. Determination of crude protein (Kjeldahl Nitrogen) in Animal feed, forage (Plant Tissue), grain & oilseeds using block digestion with copper catalyst and steam distillation into boric acid. Foss Tecator, Sweden.

Tisconia E, Bertini GC. 1973. Composition of sterol fraction of lipids extracted from oilseeds. Riv. Ital. Sost. Grasse. 50, 251–268.

Wijendran V, Hayes A. 2004. Dietary n-6 and n-3 fatty acid balance and cardiovascular health. Annu. Rev. Nutr. 24, 597–615. http://dx.doi.org/10.1146/annurev.nutr.24.012003.132106 PMid:15189133




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