The impact of saturated monoacylglycerols on the oxidative stability of Canola oil under various time/temperature conditions

Authors

DOI:

https://doi.org/10.3989/gya.0346181

Keywords:

Canola oil, Monoacylglycerols, Oxidative stability, Rancimat test, Schaal oven test

Abstract


Due to the inconsistency of monoacylglycerols’ (MAGs) impacts and the lack of research concerning the weight of saturated monoacylglycerols on the oxidative stability of oils, the current study was designed. For this purpose, saturated MAGs at 0.5, 3.0 and 5.0% were added to canola oil and subsequently exposed to a Schaall oven test at 60 °C for 31 days (to assimilate moderate thermal conditions and a prolonged treatment time) and a Rancimat test at 110 °C (to assimilate extreme thermal conditions and shorter treatment time). To evaluate the quality and oxidative stability parameters of MAG-containing canola oil, free fatty acids (FFA), peroxide value (PV), and the oxidative stability index (OSI) were determined. The findings indicated that with the increase in MAG levels, the FFA increased from 0.05 up to 0.2%. The PV increased from 2 to 100 meq/L with the increase in MAG concentration. Also, it was shown that OSI increased from 12.20 to 13.10 h, which was proportional to MAG concentration.

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References

AOCS 1996. Official Methods and Recommended Practices of the American Oil Chemists’ Society, Champaign, AOCS Press.

Aubourg SP. 2001. Effect of partially hydrolysed lipids on inhibition of oxidation of marine lipids. Euro. J. Lipid Sci. Technol. 212, 540–545.

Caponio F, Paradiso V, Bruno G, Summo C, Pasqualone A, Gomes T. 2011. Do monoacylglycerols act as pro-oxidants in purified soybean oil? Evidence of a dose-dependent effect. Ital. J. Food Sci. 23, 239.

Chen B, Mcclements DJ, Decker EA. 2011. Minor components in food oils, a critical review of their roles on lipid oxidation chemistry in bulk oils and emulsions. Crit. Rev. Food Sci. Nutr. 51, 901–916.

Chen B, Mcclements DJ, Decker EA. 2014. Impact of diacylglycerol and monoacylglycerol on the physical and chemical properties of stripped soybean oil. Food Chem. 142, 365– 372.

Colakoglu AS 2007. Oxidation kinetics of soybean oil in the presence of monoolein, stearic acid and iron. Food Chem. 101, 724–728.

Coleman RA, Lee DP. 2004. Enzymes of triacylglycerol synthesis and their regulation. Prog. Lipid Res. 43, 134–176.

Farmani J, Gholitabar A. 2015. Characterization of vanaspati fat produced in Iran. J. Am. Oil Chem. Soc. 92, 709–716.

Frega N, Mozzon M, Lercker G. 1999. Effects of free fatty acids on oxidative stability of vegetable oil. J. Am. Oil Chem. Soc. 76, 325–329.

Gomes T, Caponio F, Bruno G, Summo C, Paradiso VM. 2010. Effects of monoacylglycerols on the oxidative stability of olive oil. J. Sci. Food Agric. 90, 2228–32.

Ichinose T, Nobuyuki S, Takano H, Abe M, Sadakane K, Yanagisawa R, Ochi H, Fujioka K, Lee K-G, Shibamoto T. 2004. Liver carcinogenesis and formation of 8-hydroxy-deoxyguanosine in C3H/HeN mice by oxidized dietary oils containing carcinogenic dicarbonyl compounds. Food and Chemical Toxicology 42, 1795–1803.

Jalili F, Jafari SM, Emam-Djomeh Z, Malekjani N, Farzaneh V. 2018. Optimization of Ultrasound-Assisted Extraction of Oil from Canola Seeds with the Use of Response Surface Methodology. Food Anal. Methods 11, 598–612.

Krishnamurthy RG. 1982. Cooking oils, salad oils and salad dressings. Bailey’s Industrial Oil and Fat Products. 4th ed. New York.

Mistry BS, Min DB. 1987. Effects of Fatty Acids on the Oxidative Stability of Soybean Oil. J. Food Sci. 52, 831–832.

Mistry BS, Min DB. 1988. Prooxidant Effects of Monoglycerides and Diglycerides in Soybean Oil. J. Food Science 53, 1896–1897.

Miyashita K, Takagi T. 1986. Study on the oxidative rate and prooxidant activity of free fatty acids. J. Am. Oil Chem. Soc. 63, 1380–1384.

Naderi M, Farmani J, Rashidi L. 2015. Characterization of the Physicochemical Properties of Sunflower Oil Oleogel. Iran J. Nut. Sci. Food Tec. 10, 125–135.

Naderi M, Farmani J, Rashidi L. 2016. Structuring of Chicken Fat by Monoacylglycerols. J. Am. Oil Chem. Soc. 93, 1221– 1231.

O’Brien RD. 2008. Fats and oils, formulating and processing for applications, CRC press.

Paradiso VM, Caponio F, Bruno G, Pasqualone A, Summo C, Gomes T. 2014. Complex role of monoacylglycerols in the oxidation of vegetable oils, different behaviors of soybean monoacylglycerols in different oils. J. Agric. Food Chem. 62, 10776–10782.

Paradiso VM, Gomes T, Nasti R, Caponio F, Summo C. 2010. Effects of free fatty acids on the oxidative processes in purified olive oil. Food Res. Int. 43, 1389–1394.

Taghvaei M, Jafari SM. 2015. Application and stability of natural antioxidants in edible oils in order to substitute synthetic additives. J. Food Sci. Technol. 52, 1272–1282.

Velasco J, Dobarganes C. 2002. Oxidative stability of virgin olive oil. Euro. J. Lipid Sci. Technol. 104, 661–676.

Vichi S, Pizzale L, Conte LS, Buxaderas S, Lopez-Tamames E. 2003. Solid-phase microextraction in the analysis of virgin olive oil volatile fraction, modifications induced by oxidation and suitable markers of oxidative status. J. Agric. Food Chem. 51, 6564–71. https://doi.org/10.1021/jf030268k

Zhang Z, Wang Y, Ma X, Wang E, Liu M, Yan R. 2015. Characterisation and oxidation stability of monoacylglycerols from partially hydrogenated corn oil. Food Chem. 173, 70–9.

Zidkova J, Sajdok J, Kontrova K, Kotrbova-Kozak A, Hanis T, Zidek V, Fucikova A. 2004. Effects of oxidised dietary cod liver oil on the reproductive functions of Wistar rat. Czech J. Food Sci. 22, 108–120.

Published

2018-09-30

How to Cite

1.
Naderi M, Farmani J, Rashidi L. The impact of saturated monoacylglycerols on the oxidative stability of Canola oil under various time/temperature conditions. Grasas aceites [Internet]. 2018Sep.30 [cited 2024Apr.25];69(3):e267. Available from: https://grasasyaceites.revistas.csic.es/index.php/grasasyaceites/article/view/1735

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Research