Differential scanning calorimetry. Influence of virgin olive oil composition on its thermal profile

Authors

  • A Jiménez Márquez Estación de Olivicultura y Elaiotecnia. C.I.F.A., Jaén
  • G Beltrán Maza Estación de Olivicultura y Elaiotecnia. C.I.F.A., Jaén
  • M P Aguilera Herrera Estación de Olivicultura y Elaiotecnia. C.I.F.A., Jaén
  • M Uceda Ojeda Estación de Olivicultura y Elaiotecnia. C.I.F.A., Jaén

DOI:

https://doi.org/10.3989/gya.2007.v58.i2.75

Keywords:

Cultivars, Differential scanning calorimetry, Poliphenols, Virgin olive oil

Abstract


Samples of olive oil from the cultivars ‘Arbequina’ and ‘Picual’, with different contents in polyphenols, were analyzed by means of differential scanning calorimetry. Three speeds of cooling/heating (1, 5 and 10ºC/min) were analyzed with the differences between duplicates being lowest when the analysis was carried out at 5°C/min. An important varietal effect (p<0.05) was observed in the profiles DSC of these oils. These differences are more valuable in the profiles and values of the temperatures of the transition peaks, obtained during the melting process. Oils with medium-high (250 ppm) levels of polyphenol content showed a significant effect (p<0.05) in the values of the temperatures of the all transition peaks.

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References

Adhvaryu A; Erhan SZ; Liu ZS. y Perez JM. 2000. Oxidation kinetic studies of oils derived from unmodified and genetically modified vegetables using pressurized differential scanning calorimetry and nuclear magnetic resonance spectroscopy. Thermochim. Acta 364, 87-97. doi:10.1016/S0040-6031(00)00626-2

Beltran Maza G. 2000.Tésis Doctoral. Universidad de Jaén. Che Man YB; Haryati T; Ghazali HM, Asbi BA. 1999. Composition and thermal profile of crude Palm Oil and its products. J. Am. Oil Chem. Soc. 76, 237-242.

Coni E, Di Pasquale M, Coppolilli P, Bocca A. 1994. Detection of Animals Fats in Butter by Differential Scanning Calorimetry: A Pilot Study. J. Am. Oil Chem. Soc. 71, 807-810. doi:10.1007/BF02540453

Dyszel SM, Pettit BC. 1990. Determination of the country origin of Pistacho Nuts by DSC and HPLC. J. Am. Oil Chem. Soc. 67, 947-951. doi:10.1007/BF02541854

Gupta SK, Jaworski RJ. 1991. An evaluation of the efficacy of antioxidants in soap by Differential Scanning Calorimetry (DSC). J. Am. Oil Chem. Soc. 68, 278-279. doi:10.1007/BF02657624

Jiménez A. 2003. Resultados preliminares en la caracterización de mezclas de aceite de oliva por Calorimetría Diferencial de Barrido. Ciencia y Tecnología Alimentaria 4 (1) 47-54.

Jiménez Márquez A, Beltrán Maza G. 2003. Aplicación de la calorimetría diferencial de barrido (DSC) en la caracterización del aceite de oliva virgen. Grasas y Aceites 54, 403-409

Marikkar JMN; Lai OM; Ghazali HM and Che Man YB. 2002. Compositional and thermal analysis of RBD palm oil adulterated with lipase-catalyzed interesterified lard. Food Chem. 76, 249-258. doi:10.1016/S0308-8146(01)00257-6

Mataix J, Martínez-Victoria E. 1988. El aceite de oliva.Bases para el futuro. Ed. Consejería de Agricultura y Pesca. Junta de Andalucía.

Martínez-Suárez JM, Muñoz E, Alba J, Lanzón A. 1975. Informe sobre utilización del analizador de rendimientos Abencor. Grasas y Aceites 26, 379-385.

Nassu RT, Goncalves LAG. 1999. Determination of melting point of vegetable oils and fats by differential scanning calorimetry (DSC) technique. Grasas y Aceites 50, 16-21

Rudnik E; Szczucinska A; Gwardiak H; Szulc A, Winiarska A. 2000. Comparative studie of oxidative stability of linseed oil. Thermochim. Acta 370, 135-140. doi:10.1016/S0040-6031(00)00781-4

Reglamento CEE nº 2568/91. Características de los aceites de oliva y de los aceites de orujo de oliva y sobre sus métodos de análisis. Anexo VIII y Anexo X.

Simon P; Colman L; Niklová I, Schmidt S. 2000. Analysis of the period of oxidation of edible oils by Differential Scanning Calorimetry. J. Am. Oil Chem. Soc. 77, 639-642 doi:10.1007/s11746-000-0103-8

Tan CP, Che Man YB. 1999. Quantitative Differential Scanning Calorimetry Analysis for determining total polar compounds in heated oils. J. Am. Oil Chem. Soc. 76, 1047-1057.

Tan CP, Che Man YB. 2000. Differential Scanning Calorimetry Analysis of edible oils: comparison of thermal propierties and chemical composition. J. Am. Oil Chem. Soc. 77, 143-155 doi:10.1007/s11746-000-0024-6

Tan CP, Che Man YB. 2002. Differential scanning calorimetry analysis of palm oil, palm oil based products and coconut oil: effects of scanning rate variation. Food Chem. 76, 89-102. doi:10.1016/S0308-8146(01)00241-2

Tan CP, Che Man YB; Selamat J, Yusoff MSA. 2002. Comparative studies of oxidative stability of edible oils by differential scanning calorimetry and oxidative stability index methods. Food Chem. 76, 385-389. doi:10.1016/S0308-8146(01)00272-2

Uceda M y Hermoso M (1998). La calidad del aceite de oliva en El cultivo del olivo. Ed. Barranco D; Fernández- Escobar R., Rallo L. Ediciones Mundi-Prensa. Madrid.

Vázquez Roncero A, Janer del Valle C y Janer del Valle ML. 1973. Determinación de polifenoles totales en el aceite de oliva. Grasas y Aceites 24, 350-357.

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Published

2007-06-30

How to Cite

1.
Jiménez Márquez A, Beltrán Maza G, Aguilera Herrera MP, Uceda Ojeda M. Differential scanning calorimetry. Influence of virgin olive oil composition on its thermal profile. Grasas aceites [Internet]. 2007Jun.30 [cited 2024Apr.18];58(2):122-9. Available from: https://grasasyaceites.revistas.csic.es/index.php/grasasyaceites/article/view/75

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