Preparation and evaluation of sulphonamide nonionic surfactants

M. H. M. Ahmed

doi:10.3989/gya.053509

Autores/as

M. H. M. Ahmed Chemistry Department, Faculty of Science, Benha University

DOI:

https://doi.org/10.3989/gya.053509

Palabras clave:

Actividad biológica, Catalizador de arcilla K10, Propiedades tensoactivas, Surfactante no iónico

Resumen

Cloruros de sulfonilbenceno alquilados (octil, decil, dodecil; C₈, C₁₀ y C₁₂) fueron usados en la preparación de una nueva serie de surfactantes no iónicos (IV-VI)a-c, (VII-IX) a-c and (X-XII)a-c. Las preparaciones fueron completadas por reacción de cada cloruro de sulfonilbenceno alquilado (C₈, C₁₀ y C₁₂) con etanolamina para dar los compuestos (IIII), respectivamente. Los anteriores productos reaccionaron separadamente con óxido de etileno en presencia de diferentes catalizadores (la base KOH, el ácido de Lewis SnCl₄ y la arcilla k10) para producir secuencialmente diferentes surfactantes no iónicos con distintos moles de óxido de etileno (5, 7 y 9): (IV-VI)a-c, (VII-IX)a-c and (X-XII)a-c, respectivamente.

La estructura química de los surfactantes no iónicos preparados fueron elucidadas mediante sus espectros de IR y ¹H RMN. Las propiedades tensoactivas, biodegradabilidad y actividad biológica de los compuestos preparados fueron investigados. Los datos obtenidos muestran que estos compuestos tienen buenas propiedades tensoactivas y biológicas, así como una biodegradabilidad razonable.

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