Crystallization kinetics of safflower and olive oils during low-temperature storage
DOI:
https://doi.org/10.3989/gya.0825182Keywords:
Crystallization, Kinetic, Olive oil, Safflower oilAbstract
The crystallization behaviors of safflower and olive oils were investigated according to changes in volume and transmitted light intensity during isothermal storage at low temperature. The changes between the oils were significantly different even though their fatty acid compositions were similar, with oleic acid accounting for more than 75% (w/w) of the total oil. It was expected that minor components with high melting points would affect the crystallization behaviors of these oils. The crystallization processes of the oils were then analyzed using a kinetic model in which the oil crystallizes through two different processes. It is suggested that although the crystallization behaviors were apparently different, the crystallization mechanisms of these oils are essentially the same.
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Abeshima T. 1998. Fractionation of edible oils and fats. J. Jpn. Oil Chem. Soc. 47, 553-561. https://doi.org/10.5650/jos1996.47.553
Avrami M. 1940. Kinetics of phase change. II transformation-time relations for random distribution of nuclei. J. Chem. Phys. 8, 212-224. https://doi.org/10.1063/1.1750631
Bailey AE, Kraemer EA. 1944. Dilatometric investigations of fats I. Apparatus and techniques for fat dilatometry. Oil Soap 21, 251-253. https://doi.org/10.1007/BF02565466
Bayés-García L, Calvet T, Cuevas-Diarte MA, Ueno S. 2017. From trioleoyl glycerol to extra virgin olive oil through multicomponent triacylglycerol mixtures: Crystallization and polymorphic transformation examined with differential scanning calorimetry and X-ray diffration techniques. Food Res. Int. 99, 475-484. https://doi.org/10.1016/j.foodres.2017.06.015 PMid:28784508
Calligaris S, Arrighetti G, Barba L, Nicoli MC. 2008. Phase transition of sunflower oil as affected the oxidation level. J. Am. Oil Chem. Soc. 85, 591-598. https://doi.org/10.1007/s11746-008-1241-y
Calligaris S, Sovrano S, Manzocco L, Nicoli MC. 2006. Influence of crystallization on the oxidative stability of extra virgin olive oil. J. Agric. Food Chem. 54, 529-535. https://doi.org/10.1021/jf051808b PMid:16417316
Campbell SD, Goff HD, Rousseau D. 2004. Modeling the nucleation and crystallization kinetics of a palm stearin/ canola oil blend and lard in bulk and emulsified form. J. Am. Oil Chem. Soc. 81, 213-219. https://doi.org/10.1007/s11746-004-0884-9
Chiavaro E, Cerretani L, Paciulli M, and Vecchio S. 2012. Kinetic evaluation of non-isotermal crystallization of oxidized extra virgin olive oil. J. Therm. Anal. Calorium. 108, 799-806. https://doi.org/10.1007/s10973-011-2083-7
Coupland JN. 2002. Crystallization in emulsions. Curr. Opin. Colloid Interface Sci. 7, 445-450. https://doi.org/10.1016/S1359-0294(02)00080-8
Fujiwara M, Iwanaga Y, Yoshida H. 1972. Processing of edible oil and fat product. J. Jpn. Oil Chem. Soc. 21, 670-675. https://doi.org/10.5650/jos1956.21.670
Fulton ND, Lutton ES, Wille RL. 1954. A quick dilatometric method for control and study of plastic fats. J. Am. Oil Chem. Soc. 31, 98-103. https://doi.org/10.1007/BF02612492
Hamm W. 1995. Trends in edible oil fractionation. Trends Food Sci. Technol. 6, 121-126. https://doi.org/10.1016/S0924-2244(00)88995-5
Himawan C, Starov VM, Stapley AGF. 2006. Thermodynamic and kinetic aspects of fat crystallization. Adv. Colloid Interface Sci. 122, 3-33. https://doi.org/10.1016/j.cis.2006.06.016 PMid:16904622
Kellens M, Meeussen W, Reynaers H. 1992. Study of the polymorphism and the crystallization kinetics of tripalmitin: a microscopic approach. J. Am. Oil Chem. Soc. 69, 906-911. https://doi.org/10.1007/BF02636342
MacNaughtan W, Farhat IA, Himawan C, Starov VM, Stapley AGF. 2006. A differential scanning calorimetry study of the crystallization kinetics of tristearin-tripalmitin mixtures. J. Am. Oil Chem. Soc. 83, 1-9. https://doi.org/10.1007/s11746-006-1167-1
Miyagawa Y, Ogawa T, Nakagawa K, Adachi S. 2016. Destabilization of mayonnaise induced by lipid crystallization upon freezing. Biosci. Biotechnol. Biochem. 80, 786-790. https://doi.org/10.1080/09168451.2015.1123611 PMid:26760458
Miyagawa Y, Ogawa T, Nakagawa K, Adachi S. 2015. Effects of vegetable oil type and lipophilic emulsifiers on the induction period of fat crystallization. J. Oleo Sci. 64, 1169-1174. https://doi.org/10.5650/jos.ess15170 PMid:26468233
Miyagawa Y, Shintani K, Katsuki K, Nakagawa K, Adachi S. 2017. Thermal and structural changes of rapeseed oil during isothermal storage at low temperature. Food Structure 11, 8-15. https://doi.org/10.1016/j.foostr.2016.12.004
Miyagawa Y, Yoshida M, Chizawa Y, Adachi S. 2019. Induction periods for lipid crystallization of various vegetable oils. J. Oleo Sci. in print. https://doi.org/10.5650/jos.ess18184 PMid:30606955
Miyagawa Y, Yoshida M, Nakagawa K, Adachi S. 2018. Kinetic analysis of rapeseed oil crystallization during isothermal storage. Cryst. Growth Des. 18, 642-650. https://doi.org/10.1021/acs.cgd.7b00789
Oliveira GM de, Ribeiro APB, Santos AO dos, Cardoso LP, Kieckbusch TG. 2015. Hard fats as additives in palm oil and its relationships to crystallization process and polymorphism. LWT-Food Sci. Technol. 63, 1163-1170. https://doi.org/10.1016/j.lwt.2015.04.036
Quast LB, Luccas V, Ribeiro APB, Cardoso LP, Kieckbusch TG. 2013. Physical properties of tempered mixtures of cocoa butter, CBR and CBS fats. Int. J. Food Sci. Technol. 48, 1579-1588. https://doi.org/10.1111/ijfs.12127
Rincón-Cardona JA, Martini S, Candal RJ, Herrera ML. 2013. Polymorphic behavior during isothermal crystallization of high stearic high oleic sunflower oil stearins. Food Res. Int. 51, 86-97. https://doi.org/10.1016/j.foodres.2012.11.023
Rousseau D. 2000. Fat crystals and emulsion stability-a review. Food Res. Int. 33, 3-14. https://doi.org/10.1016/S0963-9969(00)00017-X
Timms RE. 1985. Physical properties of oils and mixtures of oils. J. Am. Oil Chem. Soc. 62, 241-249. https://doi.org/10.1007/BF02541385
Totani Y. 2012. Characteristic of fat and oil, and its application. Saiwaisyobo, Tokyo, Japan.
Turnbull D, Fisher JC. 1949. Rate of nucleation in condensed systems. J. Chem. Phys. 17, 71-73. https://doi.org/10.1063/1.1747055
Wright AJ, Narine SS, Marangoni AG. 2000. Comparison of experimental techniques used in lipid crystallization studies. J. Am. Oil Chem. Soc. 77, 1239-1242. https://doi.org/10.1007/s11746-000-0194-2
Yoshikawa S, Kida H, Matsumura Y, Sato K. 2016. Adding talc particles improves physical properties of palm oil-based shortening. Eur. J. Lipid Sci. Technol. 118, 1007-1017. https://doi.org/10.1002/ejlt.201500283
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