Kinetic and thermodynamic studies of the oil extracted from Phoenix seeds

S.  Dong; S. Sun

doi:10.3989/gya.0669221

Authors

S. Dong Lipid Technology and Engineering, School of Food Science and Engineering, Henan University of Technology https://orcid.org/0000-0001-7651-310X
S. Sun Lipid Technology and Engineering, School of Food Science and Engineering, Henan University of Technology https://orcid.org/0000-0002-3976-9250

DOI:

https://doi.org/10.3989/gya.0669221

Keywords:

Fatty acid composition, Physicochemical properties, Soxhlet extraction method, Ultrasound extraction method

Abstract

In this work, phoenix (Firmiana simplex L.) seed oil from Sterculiaceae was extracted using ultrasound-assisted and Soxhlet methods, and physicochemical properties and fatty acid composition were compared and analyzed. The kinetic and thermodynamic properties of the extraction process of Phoenix seed oil were also evaluated. The results showed that the common physicochemical properties of the oil samples extracted by the ultrasound-assisted method were lower than those of the Soxhlet extraction method. In the range of 293 K to 323 K, the effective diffusion coefficient of Phoenix seed oil was significantly different, and varied from 5.18×10^-13m²·s^-1 to 1.29×10^-12m²·s^-1. The entropy and enthalpy changes in the extraction were positive with values of 33.17 J/(mol·K) and 7.15 kJ/mol, respectively. This work provides the theoretical basis for the development of extraction process parameters and the design of an extraction process for Phoenix seed oil.

Downloads

Download data is not yet available.

References

Atapour M, Kariminia HR. 2011. Characterization and transesterification of Iranian bitter almond oil for biodiesel production. Appl. Energy. 88, 2377-2381. https://doi.org/10.1016/j.apenergy.2011.01.014

Barba FJ, Zhu ZZ, Koubaa M, Sant'Ana AS, Orlien V. 2016. Green alternative methods for the extraction of antioxidant bioactive compounds from winery wastes and by-products: A review. Trends Food Sci. Technol. 49, 96-109. https://doi.org/10.1016/j.tifs.2016.01.006

Bauman LF, Conway TF, Watson SA. 1963. Heritability of Variations in Oil Content of Individual Corn Kernels. Science. 139, 498-499. https://doi.org/10.1126/science.139.3554.498 PMid:17843877

Chen SS, Luo SZ, Zheng Z, Zhao YY, Pang M, Jiang ST. 2017. Enzymatic lipophilization of epicatechin with free fatty acids and its effect on antioxidative capacity in crude camellia seed oil. J. Sci. Food Agric. 97, 868-874. https://doi.org/10.1002/jsfa.7808 PMid:27197789

Demirbas A. 2016. Biodiesel from corn germ oil catalytic and non-catalytic supercritical methanol transesterification. Energy Sources Part A-Recovery Util. Environ. Eff. 38, 1890-1897. https://doi.org/10.1080/15567036.2015.1004388

Fernandez MB, Perez EE, Crapiste GH, Nolasco SM. 2012. Kinetic study of canola oil and tocopherol extraction: Parameter comparison of nonlinear models. J. Food Eng. 111, 682-689. https://doi.org/10.1016/j.jfoodeng.2012.01.036

Firestone D. Official method and recommended practices of the AOCS, 5th edn. AOCS Press, Champaign; 2009.

Gusniah A, Veny H, Hamzah F. 2019. Ultrasonic Assisted Enzymatic Transesterification for Biodiesel Production. Ind. Eng. Chem. Res. 58, 581-589. https://doi.org/10.1021/acs.iecr.8b03570

Gustone FD. Vegetable oils in food technology: composition, properties, and uses. Blackwell, Oxford; 2002.

James AT, Harris P, Bezard J. 1968. The inhibition of unsaturated fatty acid biosynthesis in plants by sterculic Acid. Eur. J. Biochem. 3, 318-325. https://doi.org/10.1111/j.1432-1033.1968.tb19532.x PMid:5645527

Komartin RS, Stroescu M, Chira N, Stan R, Stoica-Guzun A. 2021. Optimization of oil extraction from Lallemantia iberica seeds using ultrasound-assisted extraction. J. Food Meas. Charact. 15, 2010-2020. https://doi.org/10.1007/s11694-020-00790-w

Li BW, Wang FY, Li KY, Sun SD. 2021. Biodiesel preparation from high acid value phoenix seed oil using Eversa transform 2.0 as a novel catalyst. Biomass Convers. Biorefinery. https://doi.org/10.1007/s13399-021-01814-1

Liu XJ, Li KY, Sun SD. 2021. Biodiesel production from non-edible high acid value phoenix seed oil using a cheap immobilized lipase. Biomass Convers. Biorefinery. https://doi.org/10.1007/s13399-021-01440-x

Luddy FE, Barford RA, Herb SF, Magidman P, Riemenschneider RW. 1964 Pancreatic lipase hydrolysis of triglycerides by a semimicro technique. J. Am. Oil Chem. Soc. 41, 693-696. https://doi.org/10.1007/BF02661412

Meziane S, Kadi H. 2008. Kinetics and thermodynamics of oil extraction from olive cake. J. Am. Oil Chem. Soc. 85, 391-396. https://doi.org/10.1007/s11746-008-1205-2

Mrabet A, Rodriguez-Gutierrez G, Guillen-Bejarano R, Rodriguez-Arcos R, Sindic M, Jimenez-Araujo A. 2022. Optimization of date seed oil extraction using the assistance of hydrothermal and ultrasound technologies. Grasas Aceites. 73 (2), e457. https://doi.org/10.3989/gya.0109211

Mrabet A, Rodriguez-Gutierrez G, Guillen-Bejarano R, Rodriiguez-Arcos R, Ferchichi A, Sindic M, Jimenez-Araujo A. 2015. Valorization of Tunisian secondary date varieties (Phoenix dactylifera L.) by hydrothermal treatments: New fiber concentrates with antioxidant properties. LWT-Food Sci. Technol. 60, 518-524. https://doi.org/10.1016/j.lwt.2014.09.055

Perez EE, Carelli AA, Crapiste GH. 2011. Temperature-dependent diffusion coefficient of oil from different sunflower seeds during extraction with hexane. J. Food Eng. 105, 180-185. https://doi.org/10.1016/j.jfoodeng.2011.02.025

Politiek RGA, Bruins ME, Keppler JK, Schutyser MAI. 2022. Effect of oil content on pin-milling of soybean. J. Food Eng. 334, https://doi.org/10.1016/j.jfoodeng.2022.111149

Samaram S, Mirhosseini H, Tan CP, Ghazali HM. 2014. Ultrasound-assisted extraction and solvent extraction of papaya seed oil: Crystallization and thermal behavior, saturation degree, color and oxidative stability. Ind. Crop. Prod. 52, 702-708. https://doi.org/10.1016/j.indcrop.2013.11.047

Sulaiman S, Aziz ARA, Aroua MK. 2013. Optimization and modeling of extraction of solid coconut waste oil. J. Food Eng. 114, 228-234. https://doi.org/10.1016/j.jfoodeng.2012.08.025

Sun SD, Guo JJ, Duan X. 2019. Biodiesel preparation from Phoenix tree seed oil using ethanol as acyl acceptor. Ind. Crop. Prod. 137, 270-275. https://doi.org/10.1016/j.indcrop.2019.05.035

Sun SD, Li KY. 2020. Biodiesel production from phoenix tree seed oil catalyzed by liquid lipozyme TL100L. Renew. Energy. 151, 152-160. https://doi.org/10.1016/j.renene.2019.11.006

Sun SD, Li XL. 2016. Physicochemical properties and fatty acid profile of phoenix tree seed and its oil. J. Am. Oil Chem. Soc. 93, 1111-1114. https://doi.org/10.1007/s11746-016-2861-2

Tian ZQ, Sun SJ, Zhao XY, Yang M, Xu CH. 2018. Phoenix tree leaves-derived biomass carbons for sodium-ion batteries. Funct. Mater. Lett. 11, 6. https://doi.org/10.1142/S1793604718400088

Wang B, Sun SD, Yao N, Chu CX. 2021. A novel method for simultaneous degumming and deacidification of corn oil by miscella refining in one step. LWT-Food Sci. Technol. 137. https://doi.org/10.1016/j.lwt.2020.110480

Woo KW, Suh WS, Subedi L, Kim SY, Kim A, Lee KR. 2016. Bioactive lignan derivatives from the stems of Firmiana simplex. Bioorg. Med. Chem. Lett. 26, 730-733. https://doi.org/10.1016/j.bmcl.2016.01.008 PMid:26774654

Zhao XM, Xiang X, Huang JZ, Ma YQ, Sun JM, Zhu DZ. 2021. Studying the Evaluation Model of the Nutritional Quality of Edible Vegetable Oil Based on Dietary Nutrient Reference Intake. ACS Omega. 6, 6691-6698. https://doi.org/10.1021/acsomega.0c05544 PMid:33748582 PMCid:PMC7970471

Zhou YX, Li KY, Sun SD. 2021. Simultaneous esterification and transesterification of waste phoenix seed oil with a high free fatty acid content using a free lipase catalyst to prepare biodiesel. Biomass Bioenerg. 144. https://doi.org/10.1016/j.biombioe.2020.105930