Reactivity of the biphasic trichloroacetonitrile-CH2Cl2/H2O2 system in the epoxidation of soybean oil
DOI:
https://doi.org/10.3989/gya.2002.v53.i2.301Keywords:
Biphasic system, Epoxidation, Hydrogen peroxide, Nitrile, Soybean oilAbstract
In this work we report on the epoxidation of soybean oil by the trichloroacetonitrile -CH2Cl2/H2O2 byphasic system. The reaction was carried out at room temperature and, most importantly, in non acid conditions which prevent the opening of the oxirane ring. The epoxidized soybean oil was characterized by infrared, 1H and 13C NMR. A maximum conversion of 81 % was achieved in two hours with 86% of selectivity in epoxy groups
Downloads
Download data is not yet available.
Downloads
Published
2002-06-30
How to Cite
1.
Gerbase AE, Brasil MC, Gregório JR, Mendes AN, von Holleben MLA, Martinelli M. Reactivity of the biphasic trichloroacetonitrile-CH2Cl2/H2O2 system in the epoxidation of soybean oil. Grasas aceites [Internet]. 2002Jun.30 [cited 2024Apr.23];53(2):175-8. Available from: https://grasasyaceites.revistas.csic.es/index.php/grasasyaceites/article/view/301
Issue
Section
Research
License
Copyright (c) 2002 Consejo Superior de Investigaciones Científicas (CSIC)
This work is licensed under a Creative Commons Attribution 4.0 International License.
© CSIC. Manuscripts published in both the printed and online versions of this Journal are the property of Consejo Superior de Investigaciones Científicas, and quoting this source is a requirement for any partial or full reproduction.All contents of this electronic edition, except where otherwise noted, are distributed under a “Creative Commons Attribution 4.0 International” (CC BY 4.0) License. You may read here the basic information and the legal text of the license. The indication of the CC BY 4.0 License must be expressly stated in this way when necessary.
Self-archiving in repositories, personal webpages or similar, of any version other than the published by the Editor, is not allowed.