Extraction of antioxidants from almond-processing byproducts.

Authors

  • Ignacio Garrido Instituto de Fermentaciones Industriales (CSIC)
  • María Monagas Instituto de Fermentaciones Industriales (CSIC)
  • Carmen Gómez-Cordovés Instituto de Fermentaciones Industriales (CSIC)
  • Begoña Bartolomé Instituto de Fermentaciones Industriales (CSIC)

DOI:

https://doi.org/10.3989/gya.2007.v58.i2.76

Keywords:

Almonds, Antioxidants, ORAC-fluorescein, Polyphenols, Proanthocyanidins

Abstract


In this work, 8 different solvents/mixtures have been tested for the extraction of antioxidants from by-products derived from the industrial processing of almonds (skin or seed coating, brown hull, and green shell cover or mesocarp). The oxygen radical absorption capacity (ORAC) as well as the phenolics content of the extracts has been determined. The extracting solution methanol/HCl (1000:1, v/v) was the most effective for the almond skin and shell, whereas, for the hull, it corresponded to acetone/water (50:50, v/v), resulting in ORACFluorescein values of 0.467, 1.45 and 0.0504 mmol of Trolox/mg, respectively. At the same time, the mixtures acetone/water exhibited the highest content of total polyphenols and proanthocyanidins for the three by-products studied. Finally, results have shown that the by-products derived from almond processing, in particular, the skin and shell, posses a similar antioxidant capacity to that of grape by-products which are currently used in the development (or production) of antioxidant products.

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References

Blomhoff R. 2005. Antioxidantes y frutos secos: importancia en la prevención de las enfermedades crónicas en Salas-Salvadó J, Ros E, Sabaté J. (Ed.). Frutos secos, salud y culturas mediterraneas, 177-199. Editorial Glosa, Barcelona.

Chen CY, Milbury PE, Lapsley K, Blumberg JB. 2005. Flavonoids from almond skins are bioavailable and act synergistically with vitamins C and E to enhance hamster and human LDL resistance to oxidation. J. Nutr. 135, 1366-1373.

Dávalos A, Gómez-Cordovés C, Bartolomé B. 2004. Extending applicability of the oxygen radical absorbance capacity (ORAC-Fluorescein) assay. J. Agric. Food Chem. 52, 48-54. doi:10.1021/jf0305231

Milbury PE, Chen CY, Dolnikowski GG, Blumberg JB. 2006. Determination of flavonoids and phenolics and their distribution in almonds. J. Agric. Food Chem. 54, 5027-5033. doi:10.1021/jf0603937

Monagas M, Garrido I, Bartolome B, Gomez-Cordovés C. 2006. Chemical caracterization of commercial dietary ingredients from Vitis Vinifera L. Anal. Chim. Acta 563, 401-410. doi:10.1016/j.aca.2005.10.065

Monagas M, Hernandez-Ledesma B, Garrido I, Martin- Alvarez PJ, Gomez-Cordovés C, Bartolomé B. 2005. Quality assessment of commercial dietary antioxidant products from Vitis vinifera L. grape seeds. Nutr. Cancer 53 (2), 244-254. doi:10.1207/s15327914nc5302_13

Pinelo M, Rubilar M, Sineiro J, Núñez MJ. 2004. Extraction of antioxidant phenolics from almond hulls (Prunus amygdalus) and pine sawdust (Pinus pinaster). Food Chem. 85, 267-273. doi:10.1016/j.foodchem.2003.06.020

Ribéreau-Gayon P, Stonestreet E. 1966. Dósage des tannins du vin rouges et determination du leur structure. Chem. Anal. 48,188-196.

Salas-Salvadó J, García-Lorda P, Ros E. 2005. Fibra, frutos secos y enfermedades cardivasculares en Salas-Salvadó J, Ros E, Sabaté J. (Ed.). Frutos secos, salud y culturas mediterraneas, 157-175. Editorial Glosa, Barcelona.

Singleton VL, Rossi JA. 1965. Colorimetry of total phenolics with phosphomolibdicphosphotungstic acid reagent. Am. J. Enol. Vitic. 16, 144-158.

Siriwardhana SSKW, Shahidi F. 2002. Antiradical activity of extracts of almond and its by-products. JAOCS 79 (9), 903-908. doi:10.1007/s11746-002-0577-4

Takeoka GR, Dao LT. 2003. Antioxidants constituents of almond [Prunus dulcis (Mill.) D. A. Webb] hulls. J. Agric. Food Chem. 51, 496-501. doi:10.1021/jf020660i

Vargas FJ. 2005. Árboles productores de frutos secos. Origen, descripción, distribución y producción en Salas-Salvadó J, Ros E, Sabaté J. (Ed.). Frutos secos, salud y culturas mediterraneas, 21-54. Editorial Glosa, Barcelona.

Wijeratne SSK, Abou-Zaid MM, Shahidi F. 2006. Antioxidants polyphenols in almond and its coproducts. J. Agric. Food Chem. 54, 312-318. doi:10.1021/jf051692j

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Published

2007-06-30

How to Cite

1.
Garrido I, Monagas M, Gómez-Cordovés C, Bartolomé B. Extraction of antioxidants from almond-processing byproducts. Grasas aceites [Internet]. 2007Jun.30 [cited 2024Apr.19];58(2):130-5. Available from: https://grasasyaceites.revistas.csic.es/index.php/grasasyaceites/article/view/76

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Research