Estudios fisicoquímicos sobre mezclas de aceite de girasol con aceite de chufa prensado en frío durante el proceso de fritura
DOI:
https://doi.org/10.3989/gya.057612Palabras clave:
Ácidos Grasos, Aceite de chufa, Aceite de girasol, Antioxidantes, Estabilidad, Mezcla, Oxidación, Valor COXResumen
Aceites de girasol se mezclaron con diferentes niveles de aceite de chufa prensado en frío. Se obtuvieron mezclas de aceite de chufa con girasol en las proporciones: 0:100, 10: 90, 20: 80, 30: 70, 40: 60, 50:50 y 100: 0. Se ha evaluado el efecto del proceso sobre los parámetros físico-químicos (ácidos grasos libres (FFA), índice de peróxido (PV), índice de ácido tiobarbitúrico (TBA), índice de yodo, compuestos polares totales (TPC), color y viscosidad) tras 30 horas de fritura. Se determinó también el contenido fenólico total de los aceites originales. Mediante GLC se determinó la composición de ácidos grasos de los aceites de girasol, de chufa y las mezclas binarias de ellos, y se calculó el tipo de alteración. Los aceites originales y sus mezclas se calentaron a 180 °C ± 5 °C, a continuación, se frieron patatas pre-fritas congeladas cada 30 min. Se tomaron muestras de aceite cada 5 horas y el período completo de fritura continua fue de 30 h. Los resultados mostraron que el aceite de girasol original tenía un valor significativamente más alto de COX (7,25), mientras que el aceite de chufa presentó el valor más bajo significativamente (2,24). Las mezclas de aceite de girasol con crecientes niveles de aceite chufa lleva a aumentar la estabilidad frente a la oxidación. El contenido fenólico del aceite de chufa prensado en frío fue 3,3 veces superior que el del aceite de girasol. Los datos analíticos mostraron que el menor deterioro durante el proceso de fritura se produjo en el aceite de chufa y el más alto en el de girasol. Los cambios de los parámetros fisicoquímicos controlados fueron disminuyendo significativamente (P < 0,05) cuando las proporciones chufa / aceite de girasol variaron entre 20/80 y 50/50 (W/W). Los resultados obtenidos indican que el aceite de girasol mezclado con aceite de chufa prensado en frío aumenta la estabilidad y por lo tanto mejora la calidad del aceite de girasol durante el proceso de fritura.
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Abdel-Aal MH, Karara HA. 1986. Changes in corn oil during deep-fat frying of foods. Lebensm. Wiss. Technol. 19, 323-327.
Andrikopoulos NK, Kalogeropoulos N, Falorea A, Barbagianni, I MN. 2002. Performance of virgin olive oil and vegetable shortening during domestic deepfrying and pan-frying of potatoes. Int. J. Food Sci. Technol. 37, 177-190. http://dx.doi.org/10.1046/j.1365-2621.2002.00555.x
A.O.A.C. 2000. Official Methods of Analysis of the Association of Official Agricultural Chemists, 17th ed, Published by A.O.A.C., Washington, DC.
Aparicio R, Roda L, Albi MA, Gutiérrez F. 1999. Effect of various compounds on virgin olive oil stability measured by Rancimat J. Agric. Food Chem. 47, 4150-4155. http://dx.doi.org/10.1021/jf9812230
Ascherio A, Hennekens CH, Buring JE, Master C, Stampfer M J, Willet W.C. 1994. Trans-fatty acid intake and risk of myocardial infraction. Circulation, 89, 94-101. http://dx.doi.org/10.1161/01.CIR.89.1.94 PMid:8281700
Belewu, MA, Abodunrin OA. 2006. Preparation of Kunnu from Unexploited Rich Food Source: Tiger Nut (Cyperus esculentus). World J. Dairy Food Sci. 1, 19-21.
Belewu MA, Belewu KY 2007. Comparative Physico- Chemical evaluation of tigernut, soybean and coconut milk sources. Int. J. Agric. Biol., 5, 785-787.
Blumenthal MM. 1991. A new look at the chemistry and physics of deep – fat frying. Food Technol. 45, 68-94.
Bracco U, Dieffenbacher A, Kolarovic L.1981. Frying performance of palm oil liquid fractions. J. Am. Oil Chem. Soc. 58, 6-12. http://dx.doi.org/10.1007/BF02666044
Chan HS, Coxon D T, Peers K E, Price KR .1982.Oxidative reactions of unsaturated lipids. Food Chem. 9, 21-34. http://dx.doi.org/10.1016/0308-8146(82)90066-8
Cheikh-Rouhou S, Hentati B, Besbes S, Blecker C, Deroanne C., Attia H. 2006. Chemical Composition and Lipid Fraction Characteristics of Aleppo Pine (Pinus halepensis Mill.) Seeds Cultivated in Tunisia. Food Sci. Technol. Int. 15, 407-416. http://dx.doi.org/10.1177/1082013206069910
Chu Y H., Kung, YH. 1997. A study on oxidative stability of vegetable oil blends. Shipin Kexue. 24, 389-397.
Chu Y H, Kung Y L. 1998. A study on vegetable oil blends. Food Chem. 62, 191-195. http://dx.doi.org/10.1016/S0308-8146(97)00200-8
Codex AlimentariuS. 1999. Codex standard for named vegetable oils, CODEX STAN 210-1999, Page 1 of 16 Adopted 1999. Revisions 2001, 2003, 2009. Amendment 2005, 2011.
Cuesta C, Sánchez-Muniz F J, Garrido-Polonio S, Lopez-Varela S, Arroyo R. 1993. Thermoxidative and hydrolytic changes in sunflower oil use in frying with a fast urnover of fresh oil. J. Am. Oil Chem. Soc. 70, 1069-1073. http://dx.doi.org/10.1007/BF02632144
Fritch CW. 1981. Measurements of frying fat deterioration: A brief review. Journal of the American Oil Chemists1 Society. 58, 272- 274.
El-Anany A M, Ali Rehab F M. 2008. Use of date (Phoenix dactylifera L.) palm seed carbon as new filter aid for improving the quality of fried Sunflower oil. J. Food Technol. 6, 278-284.
El-Anany AM, Ali Rehab F M. 2012. Studies on hypolipidemic effects of Coconut oil when blended with Tiger nut oil and fed to albino rats. Grasas Aceites 63, 303-312. http://dx.doi.org/10.3989/gya.011412
Etechola E, Otaedu AC. 1996. Fatty acid compositions of tiger nut tubers (Cyperus esculentus L.) baobab seeds (Adansonia digitata L.) and their mixture. J. Am. Oil Chem. Soc. 73: 255-257. http://dx.doi.org/10.1007/BF02523905
Farag RS, El-Anany A M. 2006. Improving the quality of fried oils by using different filter aids. J. Sci. Food Agric. 86, 2228-2240. http://dx.doi.org/10.1002/jsfa.2607
Fatemi SH, Hammond EG 1980. Analysis of oleate, linoleate and linolenate hydroperoxides in oxidized ester mixtures. Lipids 15, 379-385. http://dx.doi.org/10.1007/BF02533555
Firestone D. 1997. Physical and Chemical Characteristics of Oils, Fats and Waxes, in Official Methods and Recommended Practices of the American Oil Chemists' Society, AOCS Press, Champaign, Illinois, 1997.
Garayo J., Moreira R. 2002. Vacuum frying of potato chips J. Food Eng., 55: 181-191 http://dx.doi.org/10.1016/S0260-8774(02)00062-6
Gloria H, Aguilera JM 1998. Assessment of the Quality Oils by Differential Scanning Calorimetry. J Agric. Food Chem. 46, 1363-1368. http://dx.doi.org/10.1021/jf9703664
Gómez KA, Gómez AA. 1984. Statistical procedures for agricultural 446 research. Wiley, New York.
Gordon MH, Kourimskai L. 1995. The effects of antioxidants on changes in oils during heating and deep frying. J. Sci. Food Agric. 68, 347-53. http://dx.doi.org/10.1002/jsfa.2740680314
Gutiérrez R, González-Quijano F, Dobarganes MC. 1988. An analytical procedures for the evaluation of used frying fats in: Frying of food. Principals, changes, new approaches. Eds. G. Varela, A. E. Bender, I. D. Morton, Ellis Harwood Ltd., Chichester (England).
Haryati T, Che Man YB, Ghazali HM, Asbi BA, Buana L. 1998. Determination of iodine value of palm oil based on triglyceride composition. J. Am. Oil Chem. Soc.75, 789-792. http://dx.doi.org/10.1007/s11746-998-0227-0
Hemalatha G. 2007. Sesame lignans enhance the thermal stability of edible vegetable oils. Food Chem. 105, 1076-1085. http://dx.doi.org/10.1016/j.foodchem.2007.05.023
Henna Lu FS, Tan P P. 2009. A Comparative study of storage stability in virgin coconut oil and extra virgin Olive oil upon thermal treatment. Int. Food Res. J. 16, 343-354.
Hunter JE, Applewhite TH. 1991. Reassessment of trans fatty acid availability in the US diet. Am. J. Clin. Nutr. 54, 363-369. PMid:1858700
Irwandi J, Che Man YB, Kitts DD .2000.Synergistic effect of rosemary and sage extracts and citric acid on fatty acid retention of RBD palm olein during deep-fat frying. J. Am. Oil Chem. Soc. 77, 527-533. http://dx.doi.org/10.1007/s11746-000-0084-7
Kirk RS, Sawyer R.1991. Pearson's Composition and Analysis of Foods. 9th Ed. Longman Scientific and Technical England, pp: 607-617.
Koski, A, Pekkarinen S, Hopia A, Wahala K, Heinonen M 2003. Processing of rapeseed oil: effects on sinapic acid derivative content and oxidative stability. Eur. Food Res. Technol. 217, 110-114. http://dx.doi.org/10.1007/s00217-003-0721-4
Lumley ID. 1988. Polar compounds in heated oils. In G. Varela, A. E. Bender, & I.D. Morton (Eds.), Frying of food. Principles, changes, new approaches (pp. 166-173), Chichester: Ellis Horwood Ltd.
Marina AM, Che Man YB, Nazimah SAH, Amin I. 2009. Chemical properties of coconut oil. J. Am. Oil Chem. Soc. 86, 301-307. http://dx.doi.org/10.1007/s11746-009-1351-1
Mazza G, Qi H. 1992. Effect of after-cooking darkening inhibitors on stability of frying oil and quality of French fries. J. Am. Oil Chem. Soc. 69, 847-53. http://dx.doi.org/10.1007/BF02636331
Melton SL, Jafar S, Sykes D, Trigiano MK. 1994. Review of stability measurements for frying oils and fried food flavor. J. Am. Oil. Chem. Soc. 71, 1301-1308. http://dx.doi.org/10.1007/BF02541345
Moreira RG, Castell-Pérez ME, Barrufet MA. 1999. Deep-Fat Frying: Fundamentals and Applications. An Aspen Publication, Aspen Publishers, Inc., P 3-74 Gaithersburg, Maryland. USA.
Nagao A, Yamazaki M. 1983. Lipid of Sunflower Seeds Produced in Japan, J. Am. Oil Chem. Soc. 60, 1654-1658. http://dx.doi.org/10.1007/BF02662426
Nawar WW.1969. Thermal degradation of lipids.Areview. J. Agric. Food Chem. 17, 18-21. http://dx.doi.org/10.1021/jf60161a012
Naz S, Siddiqi R, Sheikh H, Sayeed SA. 2005. Deterioration of olive, corn and soybean oils due to air, light, heat and deep-frying. Food Res. Technol. 38, 127-134.
Okafor JNC, Mordi JI, Ozumba AU, Solomon HM, Olatunji O 2003. Preliminary studies on the characterization of contaminants in tigernut (Yellow variety). In Proceedings of 27th annual Nigerian Institute of Food Science and Technology (NIFST) conference.13-17 October, 2003. pp. 210-211.
Oladele KA, Osundahunsi FO, Adebowale AY 2009. Influence of Processing Techniques on the Nutrients and anti-nutrients of Tigernut (Cyperus esculentus L.). World J. Dairy Food Sci. 2, 88-93.
Parry J, Su L, Luther M, Zhou K, Yurawetz M P, Whitetaker P.2005. Fatty acid composition and antioxidant properties of cold-pressed marionberry, boysenberry, red raspberry and blue berry seed oils. J. Agric. Food Chem. 53, 566-573. http://dx.doi.org/10.1021/jf048615t PMid:15686403
Paul S, Mittal GS. 1996. Dynamics of fat/oil degradation during frying based on physical properties. J. Food Process. Eng. 19, 201-221. http://dx.doi.org/10.1111/j.1745-4530.1996.tb00390.x
Peeled N, Gutfinger T, Letan A.1975. Effect of water and BHT on stability of cottonseed oil during frying. J. Food Sci. Agric. 26, 1655-1668. http://dx.doi.org/10.1002/jsfa.2740261106
Perkins EG. 1967. Formation of non-volatile decomposition products in heated fats and oils. Food Technol. 21, 125-130.
Przybylski R, Eskin NAM. 1995. Methods to measure volatile compounds and the flavor significance of volatile compounds. Pages 107-121 in Methods to Assess Quality and Stability of Oils and Fat-Containing Foods. K. Warner and N. A. M. Eskin, ed. AOCS Press, Champaign, IL. http://dx.doi.org/10.1201/9781439831984.ch6
Romero A, Cuesta C, Sánchez-Muniz FJ. 1998. Effect of oil replenishment during Deep fat frying of frozen foods in sunflower oil and high-oleic acid sunflower oil. J. Am. Oil Chem. Soc. 75, 161-167. http://dx.doi.org/10.1007/s11746-998-0028-5
Rotondi A, Bendini A, Cerretani L, Mari M, Lercker G, Toschi TG. 2004. Effect of olive ripening degree on the oxidative stability and organoleptic properties of Cv. Nostrana di Brisighella extra virgin olive oil. J. Agric. Food Chem. 52, 3649-3654. http://dx.doi.org/10.1021/jf049845a PMid:15161244
Saguy IS, Shani A, Weinberg P, Garti N. 1996. Utilization of jojoba oil for deep fat frying of foods. Lebensm. Wiss. Technol. 29, 573-557. http://dx.doi.org/10.1006/fstl.1996.0088
Sánchez-Muniz F J., Viejo JM, Medina R. 1992. Deep fat frying of sardines in different culinary fats. Changes in the fatty acid composition of sardines and frying fats. J. Agric. Food Chem. 40, 2252-2256. http://dx.doi.org/10.1021/jf00023a039
Shahidi F, Wanasundara UN. 2002. Methods for measuring oxidative rancidity in fats and oils. In Akon, C. C. and Min, D. B. (Eds). Food Lipids: Chemistry, Nutrition and Biotechnology, p. 387-403. New York: Marcel Dekker. http://dx.doi.org/10.1201/9780203908815.ch14
Siddique BM, Ahmad A, Ibrahim MH, Hena S, Rafatullah M, Mohd Omar AK. 2010. Physico-chemical properties of blends of palm olein with other vegetable oils. Grasas Aceites, 61, 423-429. http://dx.doi.org/10.3989/gya.010710
Sidwell CG, Harold S, Milado B, Mitchell, J H. 1954. The use of thiobarbituric acid as a measure of fat oxidation. J. Am. Chem. Soc. 31, 603-606. http://dx.doi.org/10.1007/BF02545589
Semwal AD, Murthy NMC, Sharma GK, Arya SS 1996. Studies on storage stability of commercially marketed refined sunflower oil in plastic film packs. J. Food Sci. Technol. 33, 352-354.
Su C, White P. 2004. Frying stability of high-oleate and regular soybean oil blends. J. Am. Oil. Chem. Soc. 81, 7 83-788.
Toliwal S D, Tiwari M R, Verma S. 2005. Studies on Thermal stability of Palm-Corn Oil Blends. J. Oil Technol. Assoc. India 37, 18-20.
Tompkins C, Perkins EG. 2000. Frying performance of low-linolenic acid soybean oil. J. Am. Oil Chem. Soc. 77, 223-229. http://dx.doi.org/10.1007/s11746-000-0036-2
Waltking AE, Wessels H. 1981. Chromatographic separation of polar and nonpolar components of frying oils. J. Assoc. Official Anal. Chem. 64, 1329-1330.
Warner K, Orr P, Parrott L, Glynn M. 1994. Effect of frying oil composition on potato chip stability. J. Am. Oil Chem. Soc. 71, 1117-1121. http://dx.doi.org/10.1007/BF02675905
Warner K. and Knowlton S. 1997. Frying quality and oxidative stability of high-oleic corn oils. J. Am. Oil Chem. Soc. 74, 1317-1321. http://dx.doi.org/10.1007/s11746-997-0063-7
White JP. 2000. Fatty Acids in Oilseeds. In: C K Chow (Ed.): Fatty Acids in Foods and Their Health Implications. New York: Marcel Dekker Inc., pp. 209-238. PMCid:2270112
Xu XQ, Tran H, Palmer M, White K, Salisbury P. 1999. Chemical and physical analyses and sensory evaluation of six deep-frying oils. J. Am. Oil Chem. Soc. 76, 1091-1099.
Yamsaengsung R, Moreira RG. 2002. Modelling the transport phenomena and structural changes during deep fat frying. Part II: Model solution and validation. J. Food Eng. 53, 11-25 http://dx.doi.org/10.1016/S0260-8774(01)00135-2
Yu LL, Zhou KK, Parry J. 2005. Antioxidant properties of cold-pressed black caraway, carrot, cranberry, and hemp seed oils. Food Chem. 91, 723-729. http://dx.doi.org/10.1016/j.foodchem.2004.06.044
Zhang H, Hanna MA, Ali Y, Nan L. 1996. Yellow nutsedge (Cyperus esculentus L.) tuber oil as fuel. Indus. Crops Prod. 5, 177-181. http://dx.doi.org/10.1016/0926-6690(96)89446-5
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