Estudios computacionales de propiedades físico-químicas en análisis de calidad de aceites de maíz y maní

Autores/as

DOI:

https://doi.org/10.3989/gya.0663201

Palabras clave:

Aceite de cacahuete, Aceite de maíz, Modelado potencial de LJ, Velocidad ultrasónica, Viscosidad

Resumen


Los aceites se utilizan comúnmente en la cocina como un medio para freír y se someten de forma continua a diferentes niveles de calentamiento. En este trabajo, hemos considerado dos de los aceites comunmente utilizados, como los de maní y maíz. Los análisis de calidad de los aceites de maíz y maní se han realizado relacionando propiedades macroscópicas (velocidad ultrasónica, viscosidad y densidad) con parámetros microscópicos (longitud libre intermolecular, compresibilidad adiabática, etc.) sometiéndolo a seis ciclos de calentamiento (190 ºC). La variación en las propiedades mencionadas indica el grado de degradación y su reutilización para el siguiente ciclo de calentamiento que podría ser lo usado en la industria y procesamiento de alimentos. Se utiliza la ecuación de Newton-Laplace y Wood, y a partir de los datos experimentales se estimaron la compresibilidad adiabática, la impedancia acústica y la longitud libre intermolecular de los aceites. La velocidad ultrasónica se observó estar linealmente relacionada con la viscosidad con el factor de dependencia (R2 = 0,932). Con la ayuda de los datos experimentales, se calcularon los parámetros termodinámicos físicos como el tamaño de partícula, factor de empaquetamiento, potencial químico y potencial L-J. Se observó un factor de correlación alto ajustando la velocidad, viscosidad y densidad ultrasónicas a las ecuaciones de Parthasarathy y Bakshi y Rodenbush. En el estudio, la velocidad ultrasónica, un parámetro macroscópico, podría decodificarse para determinar las variaciones microscópicas en el aceite sometido a diferentes temperaturas en una solicitud industrial.

Descargas

Los datos de descargas todavía no están disponibles.

Citas

Benedito J, Garcia-Perez JU, Dobarganes MC, Mulet A. 2007. Rapid evaluation of frying oil degradation using ultrasonic technology. Food Res. Int. 40, 406-414. https://doi.org/10.1016/j.foodres.2006.10.017

Benedito J, Mulet A, Velasco J, Dobarganes MC. 2002. Ultrasonic Assessment of oil quality during frying. J. Agri. Food Chem. 50, 4531-4536. https://doi.org/10.1021/jf020230s PMid:12137472

Brkić Bubola K, Klisović D, Lukić I, Novoselić A. 2020. Vegetable species significantly affects the phenolic composition and oxidative stability of extra virgin olive oil used for roasting. LWT 129, 109628. https://doi.org/10.1016/j.lwt.2020.109628

David William G. 2008. The Chemistry of essential oil, 2nd ed, Micelle press, UK, 248-316.

Fasina OO, Hallman H, Craig Schmidt M, Clements C. 2006. Predicting temperature - dependence viscosity of vegetable oils from fatty acid composition. J. Am. Oil Chem. Soc. 83 (10), 899-903. https://doi.org/10.1007/s11746-006-5044-8

Hemmat Esfe M, Sadati Tilebon SM. 2020. Statistical and artificial based optimization on thermo-physical properties of an oil based hybrid nanofluid using NSGA-II and RSM. Physica A. 537, 122126. https://doi.org/10.1016/j.physa.2019.122126

Heying M, Corti DS. 2004. Scaled Particle Theory Revisited: New conditions and improved predictions of the properties of the hard sphere fluid. J. Phy. Chem. B. 108, 19756 -19768. https://doi.org/10.1021/jp040398b

Izbaim D, Faiz BA, Mouden A, Taifi N, Aboudaoud I. 2010. Evaluation of the performance of the frying oils using an ultrasonic technique. Grasas Aceites 61 (2), 151-156. https://doi.org/10.3989/gya.087709

Jacobson B, Heedman PA. 1953. Intermolecular Free Lengths in the Liquid State. Acta Chem. Scand. 7, 705-712. https://doi.org/10.3891/acta.chem.scand.07-0705

Kiełczynski P, Szalewski M, Balcerzak A, Wieja K, Malanowski A, Kościesza R, Tarakowski R, Rostocki AJ, Siegoczynski RM. 2014. Determination of physicochemical properties of diacylglycerol oil at high pressure by means of ultrasonic methods. Ultrasonics 54 (8), 2134 - 40. https://doi.org/10.1016/j.ultras.2014.06.013 PMid:25017363

Lebowitz JL. 1964. Exact Solution of Generalized Percus-Yevick Equation for a Mixture of Hard Spheres. Phy. Rev. 113, A895 - A899. https://doi.org/10.1103/PhysRev.133.A895

Lennard-Jones JE. 1924. On the Determination of Molecular Fields. -II. From the Equation of State of a Gas. Proc. Royal Society London A. 106 (738), 463-477. https://doi.org/10.1098/rspa.1924.0082

Mandell MJ, Reiss H. 1975. Scaled Particle Theory: Solution to the Complete Set of Scaled Particle Theory Conditions: Applications to Surface Structure and Dilute Mixtures. J. Stat. Phys. 13 (2), 113 - 128. https://doi.org/10.1007/BF01221372

Mansoori GA, Carnahan NF, Starling KE, Leland TW. 1971. Equilibrium Thermodynamic Properties of the Mixture of Hard Spheres. J. Chem. Phy. 54 (4), 1523-1525. https://doi.org/10.1063/1.1675048

McClements JD, Gunasekaran S. 1997. Ultrasonic Characterization of Foods and Drinks: Principles, Methods, and Applications. Crit. Rev. Food Sc. Nutrit. 37 (1), 1-46. https://doi.org/10.1080/10408399709527766 PMid:9067087

Pandey JD, Kumar V, Saxena MC. 1979. Evaluation of Jacobson's Constant and Intermolecular Free-Length as a Function of Pressure and Temperature for Cryogenic Liquids. Ultrasonics 17 (4), 153-158. https://doi.org/10.1016/0041-624X(79)90032-5

Percus JK, Yevick GJ. 1958. Analysis of Classical Statistical Mechanics by Means of Collective Coordinates. Phys. Rev. 110 (1), 1-13. https://doi.org/10.1103/PhysRev.110.1

Ravi S, Amoros J, Arockia Jayalatha K. 2008. Effective method of characterizing specific liquid Fluorocarbon interactions using ultrasound. J. Phys. Chem. B. 112, 6420-6425. https://doi.org/10.1021/jp800812c PMid:18422360

Reidoon Shahidi. 2005. Bailey's Industrial oil and Fat Products, 6th ed, Wiley- Inter science Publication, vol 2. chapter 12, New york. https://doi.org/10.1002/047167849X

Reiss H, Frisch HL, Lebowitz JL. 1959. Statistical Mechanics of Rigid Spheres. J. Chem. Phys. 31 (2), 369-380. https://doi.org/10.1063/1.1730361

Rodenbush CM, Hsieh FH, Viswanatha DS. 1999. Density and Viscosity of Vegetable Oils. J. Am. Oil Chem. Soc. 76 (12), 1415-1419. https://doi.org/10.1007/s11746-999-0177-1

Rubalya Valantina S, Phebee Angeline DR, Uma S, Jeya Prakash BG. 2017. Estimation of Dielectric Constant of Oil Solution in the Quality Analysis of Heated Vegetable Oil. J. Mol. Liq. 238, 136-144. https://doi.org/10.1016/j.molliq.2017.04.107

Rubalya Valantina S, Susan D, Bavasri S, Priyadarshini V, Ramya Saraswathi R, Suriya M. 2016. Experimental investigation of electro-rheological properties of modeled vegetable oils. J. Food Sci. Tech. 53 (2), 1328-1337. https://doi.org/10.1007/s13197-015-2050-6 PMid:27162414 PMCid:PMC4837714

Rubalya Valantina S, Chandiramouli R, Neelamegam P. 2013. Detection of adulteration in olive oil using rheological and ultrasonic parameters. Inter. Food Res. J. 20 (6), 3197-3202.

Sakai T, Hirano F. 1985. Effect of molecular weight distribution of mineral oils on their boiling heat transfer behaviour. Wear 104, 259-281. https://doi.org/10.1016/0043-1648(85)90052-3

Sanaeifar A, Jafari A. 2019. Determination of the oxidative stability of olive oil using an integrated system based on dielectric spectroscopy and computer vision, Inform. Process. Agric. 6, 20-25. https://doi.org/10.1016/j.inpa.2018.08.008

Sankarappa T, Prashant Kumar M, Ahmad A. 2005. Ultrasound Velocity and Density Studies in Some Refined and Unrefined Edible Oils. Phy. Chem. Liq. 43 (6), 507-514. https://doi.org/10.1080/00319100500192889

Schössler K, Jäger H, Knorr D. 2012. Novel contact ultrasound system for the accelerated freeze-drying of vegetables. Innovative Food Sci. Emer. Tech. 16, 113-120. https://doi.org/10.1016/j.ifset.2012.05.010

Stanciu I. 2019. A new mathematical model for the viscosity of vegetable oils based on freely sliding molecules. Grasas Aceites 70 (3), e318. https://doi.org/10.3989/gya.0824182

Thiele E. 1963. Equation of state for hard spheres. J. Chem. Phy. 39 (2), 474. https://doi.org/10.1063/1.1734272

Valdes AF, Garcia AB. 2006. A study of the evolution of the physicochemical and structural characteristics of olive and sunflower oils after heating at frying temperaturas. Food Chem. 98, 214-219. https://doi.org/10.1016/j.foodchem.2005.05.061

Wen P, Tie W, Wang L, Lee MH, Li XD. 2009. Ultrasonic synthesis of 4,4'-dihydroxychalcone and its photochemical properties. Mat. Chem. Phy. 117, 1-3. https://doi.org/10.1016/j.matchemphys.2009.02.055

Wertheim MS. 1963. Exact Solution of the Percus-Yevick Integral Equation for Hard Spheres. Phys. Rev. Let. 10 (8), 321-323. https://doi.org/10.1103/PhysRevLett.10.321

Yarnell JL, Katz MJ, Wenzel RG, Koenig SH. 1973. Structure Factor and Radial Distribution Function for Liquid Argon at 85 °K. Phys. Rev. A. 7 (6), 2130-2144. https://doi.org/10.1103/PhysRevA.7.2130

Yu YX, Wu J. 2002. Structures of Hard-Sphere Fluids from a Modified Fundamental-Measure Theory. J. Chem. Phys. 117 (22), 10156-10164. https://doi.org/10.1063/1.1520530

Zhang L, Zhou C, Wang B, Yagoub AEA, Ma H, Zhang X, Wu M. 2016. Study of ultrasonic cavitation during extraction of the peanut oil at varying frequencies. Ultra. Sono. 37, 106 - 113. https://doi.org/10.1016/j.ultsonch.2016.12.034 PMid:28427612

Publicado

2021-12-30

Cómo citar

1.
Rubalya Valantina S, Arockia Jayalatha K. Estudios computacionales de propiedades físico-químicas en análisis de calidad de aceites de maíz y maní. Grasas aceites [Internet]. 30 de diciembre de 2021 [citado 2 de mayo de 2025];72(4):e427. Disponible en: https://grasasyaceites.revistas.csic.es/index.php/grasasyaceites/article/view/1913

Número

Sección

Investigación