Solvent-free synthesis of oleic acid-based wax esters using recyclable acidic deep eutectic solvent

Z.  Li; W.  Liu; G.  Yang

doi:10.3989/gya.1007202

Autores/as

Z. Li College of Food Science and Technology, Henan University of Technology https://orcid.org/0000-0001-5165-4053
W. Liu College of Food Science and Technology, Henan University of Technology https://orcid.org/0000-0003-1706-1208
G. Yang College of Food Science and Technology, Henan University of Technology https://orcid.org/0000-0002-6115-7365

DOI:

https://doi.org/10.3989/gya.1007202

Palabras clave:

Ácido p-toluensulfónico, Cera líquida, Disolventes eutécticos profundos, Esterificación, Libre de disolventes

Resumen

Las ceras se han utilizado ampliamente en productos cosméticos y farmacéuticos. Las ceras de ácido oleico se pueden utilizar para reemplazar al espermaceti o al aceite de jojoba. En este trabajo se utilizó el ácido eutéctico profundo (DES) compuesto por cloruro de colina y ácido p-toluensulfónico (1:4, mol/mol) como un catalizador reciclable eficiente para la síntesis de ceras líquida a base de ácido oleico mediante reacción de esterificación. La conversión de esterificación del alcohol cetílico podría alcanzar el 99,1% en las condiciones óptimas de reacción, mostrada como sigue: 5% de DES como catalizador, relación molar de ácido graso a alcohol de 1,3:1 y temperatura de reacción de 70 ºC durante 3 h. Es importante destacar que los experimentos de recuperación del catalizador mostraron que este catalizador DES ácido de bajo precio podría reutilizarse cinco veces con una actividad uniforme. Además, la esterificación sin disolvente catalizada por DES podría aplicarse en la preparación de otras ceras a base de ácido oleico y podrían obtenerse excelentes conversiones (> 96%) en tales condiciones suaves.

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