Preparación y caracterización de oleogeles con sebo y sebo parcialmente hidrolizado como organogeladores

Autores/as

DOI:

https://doi.org/10.3989/gya.1031192

Palabras clave:

Microestructura, Organogelador, Reología, Sebo, Sebo parcialmente hidrolizado

Resumen


El objetivo de este estudio fue evaluar el potencial de la organogelación de grasa de sebo (GS) y grasa de sebo parcialmente hidrolizada (GSH) contra monoglicéridos saturados (MG) y mezcla de monoglicéridos + diglicéridos saturados (MDG) como organogelantes. Con la propia GS se creó un oleogel con un nivel de adición del 30%, mientras que los oleogeles de GSH, MG y MDG se prepararon con niveles de adición del 10%. Los datos de composiciones de ácidos grasos mostraron que el oleogel de GSH (OGSH) era bastante similar a los oleogeles de MG y MDG. El contenido de grasa sólida, la acidez grasa libre y los valores de peróxido se encuentran en rangos aceptables para OGSH. También se evaluaron las propiedades térmicas, la morfología del cristal y los patrones de difracción de rayos X. Los análisis reológicos indicaron que todos los oleogeles tenían un módulo de almacenamiento (G´) mayor que el módulo de pérdida (G´´). La prueba de barrido de tiempo mostró que después de aplicar velocidades de cizallamiento más altas, los geles se reformaron en reposo. Además, todos los oleogeles protegieron su consistencia gelificada hasta alrededor de 54 °C de temperatura. Los resultados han sugerido que GSH podría ser un organogelador barato, eficiente, de fusión aguda, seguro y fácilmente disponible.

Descargas

Los datos de descargas todavía no están disponibles.

Citas

AOCS. 1998. Official Methods and Recommended Practices of the American Oil Chemists' Society, 5th Edn, AOCS Press, Champaigne 1998, IL.

Bot A, Veldhuizen YSJ, den Adel R, 2009. Non-TAG structuring of edible oils and emulsions. Food Hydrocol. 23, 1184-1189. https://doi.org/10.1016/j.foodhyd.2008.06.009

Bot A, Flöter E. 2018. Structuring edible oil phases with fatty acids and alcohols, in Ashok R. Patel (Ed.), Edible Oil Structuring: Concept, Methods and Applications, Royal Soc. Chem., Chambridge, UK, 95-105. https://doi.org/10.1039/9781788010184-00095

Cerqueira MA, Fasolin LH, Picone CSF, Pastrana LM, Cunha RL, Vicente AA. 2017. Structural and mechanical properties of organogels: role of oil and gelator molecular structure. Food Res. Intl. 96, 161-170. https://doi.org/10.1016/j.foodres.2017.03.021 PMid:28528095

Chrysam MM. 1996. Margarines and Spreads, in Y.H. Hui (Ed.), Bailey's Industrial Oil & Fat Products, Vol. 3, Wiley-Intersience Pub, New York, US, 65-114.

Co ED, Marangoni AG. 2012. Organogels: An alternative edible oil-structuring method. J. Am. Oil Chem. Soc. 89, 749-780. https://doi.org/10.1007/s11746-012-2049-3

Codex. 2017. Codex Alimentarius, International Food Standards, Standard for named vegetable oils, Codex Stan 210-1999.

Da Pieve S, Calligaris S, Co E, Nicoli MC, Marangoni AG. 2010. Shear nanostructuring of monoglyceride organogels. Food Biophys. 5, 211-217. https://doi.org/10.1007/s11483-010-9162-3

Dassanayake LSK, Kodali DR, Ueno S. 2011. Formation of oleogels based on edible lipid materials. Current Op. Coll. Inter. Sci. 16, 432-439. https://doi.org/10.1016/j.cocis.2011.05.005

Dassanayake LSK, Kodali DR, Ueno S, Sato K. 2009. Physical properties of rice bran wax in bulk and organogels. J. Am. Oil Chem. Soc. 86, 1163-1173. https://doi.org/10.1007/s11746-009-1464-6

Huang X, Wang J, Bi J, Hao H. 2018. Influence of diacylglycerol on physicochemical properties and crystallization behavior of palm oil. Chem. Eng. Technol. 41, 1587-1593. https://doi.org/10.1002/ceat.201700550

Kesselman E, Shimoni E. 2007. Imaging of oil/ monoglyceride networks by polarizing nearfield scanning optical microscopy. Food Biophys. 2, 117-123. https://doi.org/10.1007/s11483-007-9038-3

Love JA. 1996. Animal fats, in Y.H. Hui (Ed.), Bailey's Industrial Oil & Fat Products, Vol. 1, Wiley-Intersience Pub, New York, US, 1-18.

Mattice KD, Marangoni AG. 2018. New insights into wax crystal networks in oleogels, in Ashok R. Patel (Ed.), Edible Oil Structuring: Concept, Methods and Applications, Royal Soc. Chem., Chambridge, UK, 71-94. https://doi.org/10.1039/9781788010184-00069

Minitab. 2010. Minitab Statistical Software (Version 16.1). Minitab, Inc., State College, Pennsylvania, US.

ISO. 2008. Animal and vegetable fats and oils- Determination of solid fat content by pulsed NMR-Part 2: Indirect method. ISO/TC 34/SC 11, On-line version.

O'Brien RD. 2008. Fats and Oils: Formulating and Processing for Applications. CRC Press, New York, US. https://doi.org/10.1201/9781420061673

Öğütcü M, Yılmaz E. 2015. Characterization of hazelnut oil oleogels prepared with sunflower and carnauba waxes. Int. J. Food Prop. 18, 1741-1755. https://doi.org/10.1080/10942912.2014.933352

Patel AR, Dewettinck K. 2015. Comparative evaluation of structured oil systems: shellac oleogel, HPMC oleogel and HIPE gel. Eur. J. Lipid Sci. Technol. 117, 1772-1781. https://doi.org/10.1002/ejlt.201400553 PMid:26726293 PMCid:PMC4690198

Patel AR, Dewettinck K. 2016. Edible oil structuring: an overview and recent updates. Food Func. 7, 20-29. https://doi.org/10.1039/C5FO01006C PMid:26415120

Patel AR. 2017. Methylcellulose-coated microcapsules of palm stearine as structuring templates for creating hybrid oleogels. Mater. Chem. Phys. 195, 268-274. https://doi.org/10.1016/j.matchemphys.2017.03.059

Patel AR. 2018. Oil structuring: concepts, overview and future perspectives, in Ashok R. Patel (Ed.), Edible Oil Structuring: Concept, Methods and Applications, Royal Soc. Chem., Chambridge, UK, 3-24.

Perez-Monterroza EJP, Marquez-Cardozo CJ, Ciro-Velasquez HJ. 2014. Rheological behavior of avocado (Persea americana Mill, cv. Hass) oleogels considering the combined effect of structuring agents. LWT - Food Sci. Technol. 59, 673-679. https://doi.org/10.1016/j.lwt.2014.07.020

Rocha-Amador OG, Gallegos-Infante JA, Huang Q, Rocha-Guzman NE, Moreno-Jimenez MR, Gonzalez-Laredo RF. 2014. Influence of commercial saturated monoglyceride, mono-/ diglycerides mixtures, vegetable oil, stirring speed, and temperature on the physical properties of organogels. Int. J. Food Sci. 513641, 1-8. https://doi.org/10.1155/2014/513641 PMid:26904637 PMCid:PMC4745555

Rogers MA. 2009. Novel structuring strategies for unsaturated fats ─ Meeting the zero-trans, zero-saturated fat challenge: A review. Food Res. Int. 42, 747─753. https://doi.org/10.1016/j.foodres.2009.02.024

Sagiri SS, Samateh M, John G. 2018. Biobased molecular structuring agents, in Ashok R. Patel (Ed.), Edible Oil Structuring: Concept, Methods and Applications, Royal Soc. Chem., Chambridge, UK, 25-52. https://doi.org/10.1039/9781788010184-00023

Singh A, Auzanneau FI, Rogers MA. 2017. Advances in edible oleogel technology ─ a decade in review. Food Res. Int. 97, 307-317. https://doi.org/10.1016/j.foodres.2017.04.022 PMid:28578056

Stahl MA, Buscato MHM, Grimaldi R. 2017. Low sat-structured fats enriched in α-linolenic acid: physicochemical properties and crystallization characteristics. J. Food Sci. Technol. 54, 3391-3403. https://doi.org/10.1007/s13197-017-2780-8 PMid:29051634 PMCid:PMC5629147

Szydłowska-Czerniak A, Karlovits G, Lach M, Szłyk E. 2005. X-ray diffraction and differential scanning calorimetry studies of β'- β transitions in fat mixtures. Food Chem. 92, 133-141. https://doi.org/10.1016/j.foodchem.2004.07.010

Terech P, Weiss RG. 1997. Low molecular mass gelators of organic liquids and the properties of their gels. Chem. Rev. 97, 3133-3159. https://doi.org/10.1021/cr9700282 PMid:11851487

Toro-Vasquez JE, Charo-Alonso MA, Alvarez-Mitre, FM. 2018. Gelation properties of gelator molecules derived from 12-hydroxystearic acid, in Ashok R. Patel (Ed.), Edible Oil Structuring: Concept, Methods and Applications, Royal Soc. Chem., Chambridge, UK, 106-134. https://doi.org/10.1039/9781788010184-00106

Viriato RLS, Queiros MS, da Gama MAS, Ribeiro APB, Gigante ML. 2018. Milk fat as a structuring agent of plastic lipid bases. Food Res. Int. 111, 120-129. https://doi.org/10.1016/j.foodres.2018.05.015 PMid:30007668

Yılmaz E, Öğütcü M, Güneser O. 2015. Influence of storage on physico-chemical and volatile features of enriched and aromatized wax organogels. J. Am. Oil Chem. Soc. 92, 1429-1443. https://doi.org/10.1007/s11746-015-2719-z

Publicado

2021-02-24

Cómo citar

1.
Keskin Uslu E, Yılmaz E. Preparación y caracterización de oleogeles con sebo y sebo parcialmente hidrolizado como organogeladores. Grasas aceites [Internet]. 24 de febrero de 2021 [citado 23 de febrero de 2025];72(1):e388. Disponible en: https://grasasyaceites.revistas.csic.es/index.php/grasasyaceites/article/view/1855

Número

Sección

Investigación

Artículos más leídos del mismo autor/a